Referencing Judges 1:19 - “And the Lord was with Judah; and he drave out the inhabitants of the mountain; but could not drive out the inhabitants of the valley, because they had chariots of iron.”
And Chrysomallon squamiferum, “the only known extant animal that incorporates iron sulfide into its skeleton (into both its sclerites and into its shell as an exoskeleton)”.
https://www.sefaria.org/Judges.1.19?lang=bi&with=all&lang2=en is another translation of it which makes it seem like the team of the two of them couldn’t do it. I don’t know biblical hebrew to be able to say if that grammar is any better.